skip to main content
Idioma:
Primo Search
Clear Search Box
Search in: Busca Geral
Busca Avançada
Busca por Índices

1,1- and 1,4-Addition Reactions with 3a,6a-Diaza-1,4-diphosphapentalene Containing Two-Coordinate and Formally Divalent Phosphorus

Kornev, Alexander N. ; Galperin, Vadim E. ; Sushev, Vyacheslav V. ; Zolotareva, Natalia V. ; Baranov, Evgenii V. ; Fukin, Georgy K. ; Abakumov, Gleb A.

European journal of inorganic chemistry, 2016-08, Vol.2016 (22), p.3629-3633 [Periódico revisado por pares]

Weinheim: Blackwell Publishing Ltd

Texto completo disponível

Citações Citado por
  • Título:
    1,1- and 1,4-Addition Reactions with 3a,6a-Diaza-1,4-diphosphapentalene Containing Two-Coordinate and Formally Divalent Phosphorus
  • Autor: Kornev, Alexander N. ; Galperin, Vadim E. ; Sushev, Vyacheslav V. ; Zolotareva, Natalia V. ; Baranov, Evgenii V. ; Fukin, Georgy K. ; Abakumov, Gleb A.
  • Assuntos: Addition reactions ; Anions ; Bonding ; Cations ; Chlorides ; Coupling ; Covalence ; Hypervalent compounds ; Nitrogen heterocycles ; Phosphorus ; Phosphorus heterocycles ; Radicals
  • É parte de: European journal of inorganic chemistry, 2016-08, Vol.2016 (22), p.3629-3633
  • Notas: istex:32E9152C14562D2A3551E042AFBAD94F4685F645
    ark:/67375/WNG-XSQMH8K2-D
    Russian Science Foundation - No. 14-13-01015
    Supporting Information
    ArticleID:EJIC201600348
    ObjectType-Article-1
    SourceType-Scholarly Journals-1
    ObjectType-Feature-2
    content type line 23
  • Descrição: 3a,6a‐Diaza‐1,4‐diphosphapentalene (DDP) reacts with halocarbons to give addition products to one or both phosphorus atoms depending on the substrate. Chlorotriphenylmethane affords a 1,4‐addition product, which slowly decomposes in solution to form the Ph3C radical and the chloro‐DDP coupling product with a P–P bond. Benzyl chloride is added to one phosphorus atom to form hypervalent (trivalent, four‐coordinate) phosphorus with a N···P distance (nonvalent interaction) of 2.191(2) Å. A workup of the latter with GeCl2 results in a complex salt containing the GeCl3– anion and cation with covalent N–P bonding. DDP reacts with benzyl chloride and chlorotriphenylmethane leading to 1,1‐ and 1,4‐addition products, respectively. The 1,1‐adduct of benzyl chloride contains hypervalent phosphorus showing a N···P nonvalent interaction.
  • Editor: Weinheim: Blackwell Publishing Ltd
  • Idioma: Inglês
Voltar para lista de resultados

  • Realização: ABCD-USP USP   Logos de Redes Sociais: Freepik

Buscando em bases de dados remotas. Favor aguardar.