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Cover Feature: Through‐Space Electrostatic Interactions Surpass Classical Through‐Bond Electronic Effects in Enhancing CO2 Reduction Performance of Iron Porphyrins (ChemSusChem 5/2021)

Khadhraoui, Asma ; Gotico, Philipp ; Leibl, Winfried ; Halime, Zakaria ; Aukauloo, Ally

ChemSusChem, 2021-03, Vol.14 (5), p.1211-1211 [Periódico revisado por pares]

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Cover Feature: Through‐Space Electrostatic Interactions Surpass Classical Through‐Bond Electronic Effects in Enhancing CO2 Reduction Performance of Iron Porphyrins (ChemSusChem 5/2021)
Autor: Khadhraoui, Asma ; Gotico, Philipp ; Leibl, Winfried ; Halime, Zakaria ; Aukauloo, Ally
Assuntos: carbon dioxide ; electrocatalysis ; electrostatic interactions ; iron porphyrin ; second coordination sphere
É parte de: ChemSusChem, 2021-03, Vol.14 (5), p.1211-1211
Descrição: The Cover Feature shows an electrostatic‐assisted catalysis of carbon dioxide molecule at an iron porphyrin decorated with cationic functions in the second coordination sphere. Such functions significantly lower the overpotential of the reaction while maintaining high catalytic efficiency. This provides a new way to vault the reactivity pattern of molecular catalysts. More information can be found in the Full Paper by A. Khadhraoui et al.
Idioma: Inglês

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