Idioma:

Palladium-Catalyzed C−H Homocoupling of Thiophenes: Facile Construction of Bithiophene Structure

Masui, Kentaro ; Ikegami, Haruka ; Mori, Atsunori

Journal of the American Chemical Society, 2004-04, Vol.126 (16), p.5074-5075 [Periódico revisado por pares]

Texto completo disponível

Citações Citado por

Título:
Palladium-Catalyzed C−H Homocoupling of Thiophenes: Facile Construction of Bithiophene Structure
Autor: Masui, Kentaro ; Ikegami, Haruka ; Mori, Atsunori
Assuntos: Chemistry ; Exact sciences and technology ; Kinetics and mechanisms ; Organic chemistry ; Reactivity and mechanisms
É parte de: Journal of the American Chemical Society, 2004-04, Vol.126 (16), p.5074-5075
Notas: ark:/67375/TPS-25PRVPM1-9
istex:6BD90A713C2ADFF52679B555126508D77BC3A241
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: Palladium-catalyzed C−H homocoupling of thiophene derivatives takes place in the presence of silver(I) fluoride or acetate. A variety of bithiophenes are obtained in good to excellent yields. In particular, the reaction of 2-bromothiophene proceeds at room temperature to afford 5,5‘-dibromo-2,2‘-bithiophene, where the bromine atom is completely intact in the palladium-catalyzed reaction. XRD analysis reveals that silver fluoride is reduced to silver(0) during the reaction.
Editor: Washington, DC: American Chemical Society
Idioma: Inglês

Links

Voltar para lista de resultados