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Cavity-modified Fermi’s golden rule rate constants: Beyond the single mode approximation

Saller, Maximlian A. C. ; Lai, Yifan ; Geva, Eitan

The Journal of chemical physics, 2023-10, Vol.159 (15) [Periódico revisado por pares]

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Título:
Cavity-modified Fermi’s golden rule rate constants: Beyond the single mode approximation
Autor: Saller, Maximlian A. C. ; Lai, Yifan ; Geva, Eitan
Assuntos: Coupled modes ; Physics ; Rate constants ; Rate theory
É parte de: The Journal of chemical physics, 2023-10, Vol.159 (15)
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descrição: We extend our recently proposed theoretical framework for estimating cavity-modified equilibrium Fermi’s golden rule (FGR) rate constants beyond the single cavity mode case to cases where the molecular system is coupled to multiple cavity modes. We show that the cumulative effect of simultaneous coupling to multiple modes can enhance FGR rate constants by orders of magnitude relative to the single mode case. We also present an analysis of the conditions necessary for maximizing this effect in the Marcus limit of FGR-based rate theory.
Editor: Melville: American Institute of Physics
Idioma: Inglês

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