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Kinetics and mechanism of formyl- and acetylferrocene oxidation with molecular oxygen in organic solvents

Fomin, V. ; Shirokov, A.

Russian Journal of General Chemistry, 2012, Vol.82(6), pp.1080-1089 [Periódico revisado por pares]

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  • Título:
    Kinetics and mechanism of formyl- and acetylferrocene oxidation with molecular oxygen in organic solvents
  • Autor: Fomin, V. ; Shirokov, A.
  • Assuntos: Chemistry ; Chemistry/Food Science, General ; Chemistry
  • É parte de: Russian Journal of General Chemistry, 2012, Vol.82(6), pp.1080-1089
  • Descrição: Kinetic laws and the products of autoxidation of formyl- and acetylferrocene in organic solvents in the presence of strong and weak Brønsted acids were investigated. The special feature of the studied reactions is the extreme dependence of the metal complex oxidation rate on the strong acid concentration. This is explained by protonation of the metal complex at high concentrations of the acids leading to the formation of stable to oxidation α-ferrocenylcarbenium complexes C 5 H 5 FeC 5 H 4 C + (OH)R.
  • Idioma: Inglês

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