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Novel germanium(IV) catecholate complexes

Lado, A. ; Piskunov, A. ; Zhdanovich, I. ; Fukin, G. ; Baranov, E.

Russian Journal of Coordination Chemistry, 2008, Vol.34(4), pp.251-255 [Periódico revisado por pares]

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  • Título:
    Novel germanium(IV) catecholate complexes
  • Autor: Lado, A. ; Piskunov, A. ; Zhdanovich, I. ; Fukin, G. ; Baranov, E.
  • Assuntos: Chemistry ; Inorganic Chemistry ; Physical Chemistry ; Chemistry
  • É parte de: Russian Journal of Coordination Chemistry, 2008, Vol.34(4), pp.251-255
  • Descrição: The interaction of germanium(II) chloride dioxanate with 3,6-di- tert -butyl- o -benzoquinone or with its mono-and dianion derivatives is attended by the redox transformations. The novel germanium bis-catecholate complexes were synthesized that contained coordinated ether molecules (THF ( I ), Et 2 O ( II )) irrespective of the initial redox form of o -quinone. The germanium complex was also synthesized by the exchange reaction between GeCl 4 and sodium catecholate. Complexes ( I ), ( II ) were characterized by NMR and IR spectroscopies, elemental and X-ray diffraction analyses.
  • Idioma: Inglês

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