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Nonequilibrium Polarization of Nuclei In Photolysis of Solid Cyclohexane Solutions of Diacyl Peroxides and Ketones

Skakovskii, E. ; Shirokii, O. ; Tychinskaya, L. ; Ogorodnikova, M. ; Rykov, S.

Journal of Applied Spectroscopy, 2002, Vol.69(5), pp.689-694 [Periódico revisado por pares]

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  • Título:
    Nonequilibrium Polarization of Nuclei In Photolysis of Solid Cyclohexane Solutions of Diacyl Peroxides and Ketones
  • Autor: Skakovskii, E. ; Shirokii, O. ; Tychinskaya, L. ; Ogorodnikova, M. ; Rykov, S.
  • Assuntos: polarization of nuclei ; photolysis ; diacyl peroxide ; ketone ; solid solution
  • É parte de: Journal of Applied Spectroscopy, 2002, Vol.69(5), pp.689-694
  • Descrição: The effects of the polarization of nuclei in photolysis of solid solutions of peroxides of acetylpropionyl and acetylbenzoyl, acetone, acetone‐ d 6 , methyl ethyl ketone, cyclopentane, and cyclohexanone in cyclohexane and cyclohexane‐ d 12 are investigated. The role of the triplet states of the compounds absorbing light and of the radicals formed of them in creation of nonequilibrium polarization of the 1 H and 13 C nuclei in irradiation of these solutions has been evaluated.
  • Idioma: Inglês

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