skip to main content

Effect of Nitrogen-Containing Bases on Oxidation of Ferrocenylboric and Ferrocenylcarboxylic Acids with Hydrogen Peroxide in Water and Water–Acetonitrile Mixed Solvent

Fomin, V. ; Galkina, M. ; Kochetkova, K.

Russian Journal of General Chemistry, 2018, Vol.88(12), pp.2534-2539 [Periódico revisado por pares]

Texto completo disponível

Citações Citado por
  • Título:
    Effect of Nitrogen-Containing Bases on Oxidation of Ferrocenylboric and Ferrocenylcarboxylic Acids with Hydrogen Peroxide in Water and Water–Acetonitrile Mixed Solvent
  • Autor: Fomin, V. ; Galkina, M. ; Kochetkova, K.
  • Assuntos: ferrocenylboric acid ; ferrocenylacetic acid ; ferrocenylcarboxylic acid ; chloroquine ; ferroquine
  • É parte de: Russian Journal of General Chemistry, 2018, Vol.88(12), pp.2534-2539
  • Descrição: The effect of triethylamine and pyridine on the kinetics and mechanism of ferrocenylboric and ferrocenylcarboxylic acids oxidation with hydrogen peroxide in water and aqueous-organic media has been studied. The addition of amines has accelerated the oxidation of ferrocenylboric acid both by hydrogen peroxide and by oxygen. Triethylamine has slowed down the oxidation of ferrocenylacetic acid and stabilized the formed zwitter-ion Fc + CH 2 COO – . Ferrocenylcarboxylic acid has not been oxidized by H 2 O 2 . The mechanism of the reaction has been suggested.
  • Idioma: Inglês

Buscando em bases de dados remotas. Favor aguardar.