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Kinetics and mechanism of oxidation with peroxides of ferrocenylacetic acid and methyl ferrocenylacetate

Fomin, V. ; Volkova, A. ; Orlova, E. ; Zaitseva, K.

Russian Journal of General Chemistry, 2013, Vol.83(5), pp.949-958 [Periódico revisado por pares]

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  • Título:
    Kinetics and mechanism of oxidation with peroxides of ferrocenylacetic acid and methyl ferrocenylacetate
  • Autor: Fomin, V. ; Volkova, A. ; Orlova, E. ; Zaitseva, K.
  • É parte de: Russian Journal of General Chemistry, 2013, Vol.83(5), pp.949-958
  • Descrição: The reaction of ferrocenylacetic acid and its methyl ester with peroxides ROOR (R = H, t -Bu) in organic solvents was studied. It is shown that direct involvement of the substituent in this process leads to abnormally high reactivity of the acid toward H 2 O 2 and t -BuOOH as compared with both the ester and ferrocene in a model system of Cp 2 Fe + PhCOOH. An unusual shift of the absorption maximum of the ferrocenyl cation formed in the reaction course to longer wavelengths reaching up to several tens of nanometers was discovered.
  • Idioma: Inglês

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