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Investigation of photochemical transformations of tetrathiafulvalene-bridged di- o -quinone

Klement’eva, S. ; Fukin, G. ; Baranov, E. ; Cherkasov, V. ; Abakumov, G.

High Energy Chemistry, 2011, Vol.45(5), pp.423-427 [Periódico revisado por pares]

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  • Título:
    Investigation of photochemical transformations of tetrathiafulvalene-bridged di- o -quinone
  • Autor: Klement’eva, S. ; Fukin, G. ; Baranov, E. ; Cherkasov, V. ; Abakumov, G.
  • Assuntos: Radiation (Physics) -- Chemical Properties ; Photolysis -- Chemical Properties
  • É parte de: High Energy Chemistry, 2011, Vol.45(5), pp.423-427
  • Descrição: It has been found that irradiation of tetrathiafulvalene-bridged di- o -quinone with visible light leads to the successive decarbonylation of the o -benzoquinone fragments. The molecular structure of the final product dicyclopentadienone has been established by X-ray diffraction measurements. The features of the photoconversion kinetics of the substrate di- o -quinone and the intermediate product of its photolysis in benzene solutions by the action of 546-nm monochromatic radiation have been revealed.
  • Idioma: Inglês

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