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Crystal structure of bis-(aceto-nitrile-κ)(4,4'-di--butyl-2,2'-bi-pyridine-κ,')platinum(II) bis-(tetra-fluorido-borate) packing as head-to-head dimers

Joseph, Chris ; Nesterov, Vladimir N ; Smucker, Bradley W

Acta crystallographica. Section E, Crystallographic communications, 01 May 2018, Vol.74(Pt 5), pp.695-697 [Periódico revisado por pares]

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  • Título:
    Crystal structure of bis-(aceto-nitrile-κ)(4,4'-di--butyl-2,2'-bi-pyridine-κ,')platinum(II) bis-(tetra-fluorido-borate) packing as head-to-head dimers
  • Autor: Joseph, Chris ; Nesterov, Vladimir N ; Smucker, Bradley W
  • Assuntos: Crystal Structure ; Platinum(II) ; Supra­molecular
  • É parte de: Acta crystallographica. Section E, Crystallographic communications, 01 May 2018, Vol.74(Pt 5), pp.695-697
  • Descrição: The crystal structure of a platinum(II) supra-molecular building block, [Pt(dbbpy)(NCCH)](BF) (dbbpy = 4,4'-di--butyl-2,2'-bi-pyridine, CHN) is an example of a rare head-to-head dimer, even with the bulky -butyl groups of the bi-pyridine. This packing motif still enables significant π-π inter-actions between two pyridyl groups, and may result from the close proximity of the tetra-fluorido-borate ions to the platinum(II) complexes, resulting in intra-molecular H⋯F distances between 2.156 and 2.573 Å.
  • Idioma: Inglês

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