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5,10,15,20-Tetra-kis(4-meth-oxy-phen-yl)porphyrinatozinc di-chloro-methane disolvate

Mcgill, Sean ; Nesterov, Vladimir N ; Gould, Stephanie L

Acta crystallographica. Section E, Structure reports online, 2013, Vol.69(Pt 8), pp.m471 [Periódico revisado por pares]

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  • Título:
    5,10,15,20-Tetra-kis(4-meth-oxy-phen-yl)porphyrinatozinc di-chloro-methane disolvate
  • Autor: Mcgill, Sean ; Nesterov, Vladimir N ; Gould, Stephanie L
  • Assuntos: Engineering ; Chemistry
  • É parte de: Acta crystallographica. Section E, Structure reports online, 2013, Vol.69(Pt 8), pp.m471
  • Descrição: In the title compound, [Zn(C48H36N4O4)]·2CH2Cl2, the Zn(II) ion lies on an inversion center and is coordinated in an almost ideal square-planar geometry. The asymmetric unit also contains one di-chloro-methane solvent mol-ecule. The unique meth-oxy-substituted benzene rings form dihedral angles of 59.38 (6) and 66.77 (6)° with the mean plane (r.m.s. deviation of fitted atoms = 0.0282 Å) of the atoms in the porphyrin core. The packing is characterized by close contacts between the Zn(II) ion and two symmetry-related mol-ecules through the O atoms of a meth-oxy-phenyl group [Zn⋯O = 2.694 (2) Å], forming a two-dimensional network parallel to (100).
  • Idioma: Inglês

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