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5,10,15,20-Tetra-kis(4-tol-yl)porphyrinzinc(II) dichloro-methane solvate

Mcgill, Sean ; Nesterov, Vladimir N ; Gould, Stephanie L

Acta crystallographica. Section E, Structure reports online, 05 June 2010, Vol.66(Pt 7), pp.m723 [Periódico revisado por pares]

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  • Título:
    5,10,15,20-Tetra-kis(4-tol-yl)porphyrinzinc(II) dichloro-methane solvate
  • Autor: Mcgill, Sean ; Nesterov, Vladimir N ; Gould, Stephanie L
  • Assuntos: Metal-Organic Papers
  • É parte de: Acta crystallographica. Section E, Structure reports online, 05 June 2010, Vol.66(Pt 7), pp.m723
  • Descrição: In the title complex, [Zn(C(48)H(36)N(4))]·CH(2)Cl(2), the Zn(II) atom lies on an inversion center and the dichloro-methane solvent mol-ecule is disordered around an inversion center. The tolyl substituents are twisted compared to the central aromatic ring system of the porphyrin, similar to what is seen in previously published structures of this molecule [Dastidar & Goldberg (1996 ▶). Acta Cryst. C52, 1976-1980]. The dihedral angles between the mean planes of the tolyl rings and the central ring are 66.98 (6) and 60.40 (6)°.
  • Idioma: Inglês

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