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Effect of Nitrogen-Containing Bases on Oxidation of Ferrocenylboric and Ferrocenylcarboxylic Acids with Hydrogen Peroxide in Water and Water--Acetonitrile Mixed Solvent.(Report)

Fomin, V. M. ; Galkina, M. S. ; Kochetkova, K. S.

Russian Journal of General Chemistry, 2018, Vol.88(12), p.2534(6) [Periódico revisado por pares]

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  • Título:
    Effect of Nitrogen-Containing Bases on Oxidation of Ferrocenylboric and Ferrocenylcarboxylic Acids with Hydrogen Peroxide in Water and Water--Acetonitrile Mixed Solvent.(Report)
  • Autor: Fomin, V. M. ; Galkina, M. S. ; Kochetkova, K. S.
  • Assuntos: Amines ; Hydrogen Peroxide ; Oxidation-Reduction Reactions ; Acetonitrile ; Pyridine
  • É parte de: Russian Journal of General Chemistry, 2018, Vol.88(12), p.2534(6)
  • Descrição: Byline: V. M. Fomin (1), M. S. Galkina (1), K. S. Kochetkova (1) Keywords: ferrocenylboric acid; ferrocenylacetic acid; ferrocenylcarboxylic acid; chloroquine; ferroquine Abstract: The effect of triethylamine and pyridine on the kinetics and mechanism of ferrocenylboric and ferrocenylcarboxylic acids oxidation with hydrogen peroxide in water and aqueous-organic media has been studied. The addition of amines has accelerated the oxidation of ferrocenylboric acid both by hydrogen peroxide and by oxygen. Triethylamine has slowed down the oxidation of ferrocenylacetic acid and stabilized the formed zwitter-ion [Fc.sup.+]C[H.sub.2]COO.sup.--. Ferrocenylcarboxylic acid has not been oxidized by [H.sub.2]O.sub.2. The mechanism of the reaction has been suggested. Author Affiliation: (1) 0000 0001 0344 908X, grid.28171.3d, Lobachevsky State University of Nizhny Novgorod, pr. Gagarina 23, Nizhny Novgorod, 603950, Russia Article History: Registration Date: 26/03/2018 Received Date: 08/05/2018 Accepted Date: 11/05/2018 Online Date: 28/03/2019 Article note: Original Russian Text [c] V.M. Fomin, M.S. Galkina, K.S. Kochetkova, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 12, pp. 2018--2023.
  • Idioma: Inglês

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