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Features of autoxidation of ferrocenylcarboxylic acid and its methyl ester in organic solvents in the presence of Bronsted acids.(Report)

Fomin, V. M. ; Shirokov, A. E.

Russian Journal of General Chemistry, 2013, Vol.83(2), p.289(10) [Periódico revisado por pares]

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  • Título:
    Features of autoxidation of ferrocenylcarboxylic acid and its methyl ester in organic solvents in the presence of Bronsted acids.(Report)
  • Autor: Fomin, V. M. ; Shirokov, A. E.
  • Assuntos: Metallocenes ; Dioxane ; Iron Compounds
  • É parte de: Russian Journal of General Chemistry, 2013, Vol.83(2), p.289(10)
  • Descrição: To access, purchase, authenticate, or subscribe to the full-text of this article, please visit this link: http://dx.doi.org/10.1134/S1070363213020102 Byline: V. M. Fomin (1681), A. E. Shirokov (1681) Keywords: Dioxane; General Chemistry; Ferrocene; Carboxy Group; Ferrocenyl Abstract: We have studied the autoxidation of ferrocenecarboxylic acid and its methyl ester in organic solvents in the presence of perchloric and trifluoroacetic acids. Based on the results of kinetic studies and data on the composition of the reaction products, we suggested the possible reaction mechanisms, including those of molecular and radical-chain macrostages of the process. The features of the solvent influence on the rate of oxidation of metallocomplexes and the reasons for its extreme dependence with increasing concentration of perchloric acid are discussed. Author Affiliation: (1681) 0000 0001 0344 908X, grid.28171.3d, Lobachevskii Nizhny Novgorod State University, pr. Gagarina 23, Nizhny Novgorod, 603950, Russia Article History: Registration Date: 12/03/2013 Received Date: 26/12/2011 Online Date: 01/02/2013 Article note: Original Russian Text [c] V.M. Fomin, A.E. Shirokov, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 2, pp. 235--244.
  • Idioma: Inglês

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