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Artificial holoenzymes for benzoin condensation using thiazolio-appended β-cyclodextrin dimers

Ikeda, Hiroshi ; Horimoto, Yasuhide ; Nakata, Machiko ; Ueno, Akihiko

Tetrahedron letters, 2000-08, Vol.41 (33), p.6483-6487 [Periódico revisado por pares]

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Título:
Artificial holoenzymes for benzoin condensation using thiazolio-appended β-cyclodextrin dimers
Autor: Ikeda, Hiroshi ; Horimoto, Yasuhide ; Nakata, Machiko ; Ueno, Akihiko
Assuntos: biomimetic reactions ; cyclodextrins ; host compounds ; supramolecular chemistry
É parte de: Tetrahedron letters, 2000-08, Vol.41 (33), p.6483-6487
Descrição: Artificial holoenzymes for benzoin condensation were synthesized using thiazolio-appended β-cyclodextrin dimers. The dimer with an l-aspartic acid residue as a linker for connecting two β-cyclodextrin units caused a 26-fold acceleration in the benzoin condensation, whereas the dimer with the linker of a l-glutamic acid residue caused only a 7-fold acceleration, indicating that the linker length of the dimer is an important factor in this artificial holoenzyme.
Editor: Elsevier Ltd
Idioma: Inglês

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