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A New Empirical Relation between the Enthalpy of Vaporization and (Tc − Tm) for the Liquids of Similar Chemical Groups (Tc: Critical Temperature, Tm: Melting Temperature)

Kanno, Hitoshi

Bulletin of the Chemical Society of Japan, 2017-04, Vol.90 (4), p.422-426 [Periódico revisado por pares]

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Título:
A New Empirical Relation between the Enthalpy of Vaporization and (Tc − Tm) for the Liquids of Similar Chemical Groups (Tc: Critical Temperature, Tm: Melting Temperature)
Autor: Kanno, Hitoshi
Assuntos: Critical temperature ; Enthalpy ; Liquids ; Melt temperature ; Organic chemistry ; Transition temperature ; Vaporization
É parte de: Bulletin of the Chemical Society of Japan, 2017-04, Vol.90 (4), p.422-426
Descrição: A new empirical linear relation between the enthalpy of vaporization and (Tc − Tm) (Tc: critical temperature, Tm: melting temperature) is presented for liquids of similar chemical groups. Combination of the above finding with Trouton’s rule leads to another linear relation between Tb (boiling temperature) and (Tc − Tm). As an extension, a different expression for the Guldberg rule is also derived. These findings can contribute to the understanding of general behavior of liquids and the development of theories of liquids.
Editor: Tokyo: The Chemical Society of Japan
Idioma: Inglês

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