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Temperature programmed X-ray photoelectron spectroscopy: a new technique for the study of surface kinetics

Baraldi, A. ; Comelli, G. ; Lizzit, S. ; Cocco, D. ; Paolucci, G. ; Rosei, R.

Surface science, 1996-12, Vol.367 (3), p.L67-L72 [Periódico revisado por pares]

Lausanne: Elsevier B.V

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Título:
Temperature programmed X-ray photoelectron spectroscopy: a new technique for the study of surface kinetics
Autor: Baraldi, A. ; Comelli, G. ; Lizzit, S. ; Cocco, D. ; Paolucci, G. ; Rosei, R.
Assuntos: Adsorbed layers and thin films ; Atom-solid interactions, scattering, diffraction ; Carbon monoxide ; Chemisorption ; Chemistry ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Construction and use of effective interatomic interactions ; Electron and ion emission by liquids and solids; impact phenomena ; Exact sciences and technology ; General and physical chemistry ; Low index single crystal surfaces ; Metallic surfaces ; Models of surface kinetics ; Photoelectron emission ; Photoemission and photoelectron spectra ; Physics ; Rhodium ; Soft X-ray photoelectron spectroscopy ; Solid-gas interface ; Surface physical chemistry ; Surface structure, morphology, roughness, and topography ; Thermal desorption ; Thermal desorption spectroscopy
É parte de: Surface science, 1996-12, Vol.367 (3), p.L67-L72
Notas: ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
Descrição: The desorption of CO from the (2 × 1)p2mg layer on Rh(110) was studied by means of a novel method — temperature-programmed X-ray photoelectron spectroscopy (TPXPS). The new information on the variation of the concentration of top and bridge CO during thermal desorption was used to evaluate the difference of the adsorption enthalpies. A model for the structural evolution of the adsorbed layer is suggested, taking into account the CO bonding configurations and the role of the CO CO repulsive interactions.
Editor: Lausanne: Elsevier B.V
Idioma: Inglês

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Temperature programmed X-ray photoelectron spectroscopy: a new technique for the study of surface kinetics

Baraldi, A. ; Comelli, G. ; Lizzit, S. ; Cocco, D. ; Paolucci, G. ; Rosei, R.

Lausanne: Elsevier B.V

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