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Asymmetric synthesis of diarylmethylamines: preparation of selective opioid delta receptor ligands

Delorme, Daniel ; Berthelette, Carl ; Lavoie, Rico ; Roberts, Edward

Tetrahedron: asymmetry, 1998-11, Vol.9 (22), p.3963-3966 [Periódico revisado por pares]

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Título:
Asymmetric synthesis of diarylmethylamines: preparation of selective opioid delta receptor ligands
Autor: Delorme, Daniel ; Berthelette, Carl ; Lavoie, Rico ; Roberts, Edward
É parte de: Tetrahedron: asymmetry, 1998-11, Vol.9 (22), p.3963-3966
Descrição: Two different methods were used for the construction of optically active diarylmethylamines. Diastereoselective alkylation on an aldimine/oxazolidine 2a/ 2b derived from ( R)/( S)-phenylglycinol or enantioselective reduction of 4-[η 6-chromium tricarbonylbenzoyl] bromobenzene using chiral oxazoborolidine followed by amine introduction to furnish optically active diarylmethylamines.
Editor: Elsevier Ltd
Idioma: Inglês

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