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Direct access to trifluoromethylated α-hydroxyketones from silver-catalyzed hydroacyloxylation of trifluoromethyl propynols with acids

Song, Xiao-Fang ; Zhang, Li-Jing ; Zhang, Xing-Guo ; Tu, Hai-Yong

Tetrahedron, 2023-01, Vol.130, p.133166, Article 133166 [Periódico revisado por pares]

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Título:
Direct access to trifluoromethylated α-hydroxyketones from silver-catalyzed hydroacyloxylation of trifluoromethyl propynols with acids
Autor: Song, Xiao-Fang ; Zhang, Li-Jing ; Zhang, Xing-Guo ; Tu, Hai-Yong
Assuntos: Hydroacyloxylation ; Silver catalysis ; Trifluoromethyl propynols ; Trifluoromethylated α-hydroxyketones
É parte de: Tetrahedron, 2023-01, Vol.130, p.133166, Article 133166
Descrição: A general and efficient method for the synthesis of trifluoromethylated α-acyloxyketones has been developed via silver-catalyzed hydroacyloxylation of trifluoromethyl propynols with a variety of acids. The obtained α-acyloxyketones can be easily hydrolyzed under acidic conditions to afford the corresponding trifluoromethylated α-hydroxyketones, and undergoes various further transformations. [Display omitted]
Editor: Elsevier Ltd
Idioma: Inglês

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