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The First Zwitterionic, Optically Active Disilicate with Pentacoordinate Silicon

Tacke, Reinhold ; Mühleisen, Mathias ; Jones, Peter G.

Angewandte Chemie (International ed.), 1994-06, Vol.33 (11), p.1186-1188 [Periódico revisado por pares]

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Título:
The First Zwitterionic, Optically Active Disilicate with Pentacoordinate Silicon
Autor: Tacke, Reinhold ; Mühleisen, Mathias ; Jones, Peter G.
Assuntos: Chemistry ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Organic chemistry ; Organic compounds ; Organometalloidal and organometallic compounds ; Physics ; Preparations and properties ; Si derivatives ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids
É parte de: Angewandte Chemie (International ed.), 1994-06, Vol.33 (11), p.1186-1188
Notas: istex:DCE338B0367A41BE8A6B2DC58BE3F2B076896875
This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie.
ark:/67375/WNG-T7XBHC19-K
ArticleID:ANIE199411861
Descrição: Stereospecifically and with surprising ease, the first zwitterionic λ5Si,λ5Si′‐disilicate ( + )‐1 was prepared from (EtO)3SiCH2NH2 and (R,R)‐(+)‐tartaric acid in aqueous solution. The binuclear complex is optically active owing to the two chiral units and the tetradentate tartrato ligands.
Editor: Zug: Hüthig & Wepf Verlag
Idioma: Inglês

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