Idioma:

The unimolecular isomerisation of monofluorocyclopropane: a reaction with multiple fall-off characteristics?

Baghal-Vayjooee, Mohammad H ; Yau, Andrew W ; Pritchard, Huw O

Canadian journal of chemistry, 1977-05, Vol.55 (10), p.1595-1598 [Periódico revisado por pares]

Texto completo disponível

Citações Citado por

Título:
The unimolecular isomerisation of monofluorocyclopropane: a reaction with multiple fall-off characteristics?
Autor: Baghal-Vayjooee, Mohammad H ; Yau, Andrew W ; Pritchard, Huw O
É parte de: Canadian journal of chemistry, 1977-05, Vol.55 (10), p.1595-1598
Descrição: Monofluorocyclopropane isomerises at 475 °C to give four products, cis-1-fluoropropene, trans-1-fluoropropene, 2-fluoropropene, and 3-fluoropropene; the ratios of product formation are not independent of pressure and it is shown that, using the Kassel representation, the individual fall-off curves correspond to values of the parameter s = 9, 6, 4, and 4 respectively. It is shown that although conventional RRKM theory can account satisfactorily for the difference in fall-off behaviour between the cis- and trans-1-propene yields, it cannot account for the pressure dependence of the formation of 2- and 3-fluoropropene; the latter behaviour is, however, easily understood in terms of the master-equation approach.
Editor: Ottawa, Canada: NRC Research Press
Idioma: Inglês

Voltar para lista de resultados