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Partial oxidation of methane by nitrous oxide over molybdenum on silica

Liu, H. F ; Liu, R. S ; Liew, K. Y ; Johnson, R. E ; Lunsford, J. H

J. Am. Chem. Soc.; (United States), , Vol.106 (15), p.4117-4121 [Periódico revisado por pares]

Washington, DC: American Chemical Society

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Título:
Partial oxidation of methane by nitrous oxide over molybdenum on silica
Autor: Liu, H. F ; Liu, R. S ; Liew, K. Y ; Johnson, R. E ; Lunsford, J. H
Assuntos: 400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987) ; ALKANES ; CATALYSIS ; CATALYTIC EFFECTS ; CHALCOGENIDES ; CHEMICAL REACTION KINETICS ; CHEMICAL REACTIONS ; Chemistry ; DATA ; ELECTRON SPIN RESONANCE ; ELEMENTS ; Exact sciences and technology ; EXPERIMENTAL DATA ; HETEROGENEOUS CATALYSIS ; HYDROCARBONS ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; KINETICS ; Kinetics and mechanisms ; MAGNETIC RESONANCE ; METALS ; METHANE ; MOLYBDENUM ; NITROGEN COMPOUNDS ; NITROGEN OXIDES ; NITROUS OXIDE ; NUMERICAL DATA ; Organic chemistry ; ORGANIC COMPOUNDS ; OXIDATION ; OXIDES ; OXYGEN COMPOUNDS ; RADICALS ; REACTION KINETICS ; Reactivity and mechanisms ; RESONANCE ; TRANSITION ELEMENTS
É parte de: J. Am. Chem. Soc.; (United States), , Vol.106 (15), p.4117-4121
Notas: ark:/67375/TPS-6ZMKR4N4-7
istex:C6D9941AD2EE397C0741F3E0A367D1F382128BED
Descrição: Kinetic data are presented for the partial oxidation of methane to methanol and formaldehyde by nitrous oxide catalysed by molybdenum supported on silica when steam is present in the system. The data are used as evidence to show how the selective oxidation mechanism fits into an overall reaction scheme. Moreover, in support of this selective mechanism, spectroscopic evidence is given for the formation of methyl radicals and methoxide ions on the surface. 12 references, 7 figures, 1 table.
Editor: Washington, DC: American Chemical Society
Idioma: Inglês

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Partial oxidation of methane by nitrous oxide over molybdenum on silica

Liu, H. F ; Liu, R. S ; Liew, K. Y ; Johnson, R. E ; Lunsford, J. H

Washington, DC: American Chemical Society

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