OH− Conductive Properties and Water Uptake of Anion Exchange
Thin
Films
ABCD PBi
OH− Conductive Properties and Water Uptake of Anion Exchange
Thin
Films
Autor:
Wang, Fangfang
;
Wang, Dongjin
;
Nagao, Yuki
Materias:
Anion exchanging
;
Benzene
;
electrolytes
;
fuel cells
;
In situ measurement
;
Ionomers
;
Membranes
;
OH− conductivity
;
Proton conduction
;
Relative humidity
;
Thin
films
;
Water chemistry
;
water uptake
Es parte de:
ChemSusChem, 2021-07, Vol.14 (13), p.2694-2697
Notas:
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
Descripción:
Several investigations have indicated that proton conduction and hydration properties of acidic ionomers differ from those of membranes. However, relations between the OH− conductivity and water uptake in
thin
film forms of anion exchange membranes have not been reported yet. For this study, new in situ measurements were established to elucidate the OH− conductivity and water uptake without allowing any influence of CO2 from the air. Poly[(9,9‐bis(6′‐(N,N,N‐trimethylammonium)‐hexyl)‐9H‐fluorene)‐alt‐(1,4‐benzene)], denoted as PFB+, was synthesized as a model ionomer. The highest OH− conductivity of 273 nm‐thick PFB+ film was 5.3×10−2 S cm−1 at 25 °C under 95 % relative humidity (RH), which is comparable to the reported OH− conductivity of PFB+ membrane. Reduced OH− conductivity was found in the thinner film at 95 % RH. The decreased OH− conductivity is explainable by the reduced number of water molecules contained in the thinner film. The OH− conductivity was reduced only slightly under the same water uptake. Anion exchange: Poly[(9,9‐bis(6′‐(N,N,N‐trimethylammonium)‐hexyl)‐9H‐fluorene)‐alt‐(1,4‐benzene)] (PFB+) is used as a model ionomer to investigate the OH− conductivity and water uptake in thin film form. Reduced OH− conductivity is observed in the thinner film at 95 % relative humidity, which can be attributed to the decreased amount of water content. The OH− conductivity is only slightly reduced under the same water uptake.
Editor:
Germany: Wiley Subscription Services, Inc
Idioma:
Inglés