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A Gold(I)‐Catalyzed Tandem Cyclization to Benzoindenodiazepines from o‐Phenylenediamines and Ynones

Xie, Fukai ; Zhang, Bo ; Chen, Yanyu ; Jia, Hongwei ; Sun, Lei ; Zhuang, Kaitong ; Yin, Lili ; Cheng, Maosheng ; Lin, Bin ; Liu, Yongxiang

Advanced synthesis & catalysis, 2020-09, Vol.362 (18), p.3886-3897 [Periódico revisado por pares]

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Título:
A Gold(I)‐Catalyzed Tandem Cyclization to Benzoindenodiazepines from o‐Phenylenediamines and Ynones
Autor: Xie, Fukai ; Zhang, Bo ; Chen, Yanyu ; Jia, Hongwei ; Sun, Lei ; Zhuang, Kaitong ; Yin, Lili ; Cheng, Maosheng ; Lin, Bin ; Liu, Yongxiang
Assuntos: Gold
É parte de: Advanced synthesis & catalysis, 2020-09, Vol.362 (18), p.3886-3897
Descrição: A gold‐catalyzed tandem cyclization of o‐phenylenediamines with ynones to synthesize benzo[b]indeno[1,2‐e][1,4]diazepine has been developed. The mechanism was explored by control experiments. The method provides a way to access a range of benzo[b]indeno[1,2‐e][1,4]diazepine derivatives in diversity‐oriented synthesis aiming at discovering structurally diverse scaffolds.
Editor: Heidelberg: Wiley Subscription Services, Inc
Idioma: Inglês

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