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Visible-Light-Promoted Conversion of Alkyl Benzyl Ether to Alkyl Ester or Alcohol via O‑α-sp3 C–H Cleavage

Lu, Ping ; Hou, Tianyuan ; Gu, Xiangyong ; Li, Pixu

Organic letters, 1900 [Periódico revisado por pares]

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Título:
Visible-Light-Promoted Conversion of Alkyl Benzyl Ether to Alkyl Ester or Alcohol via O‑α-sp3 C–H Cleavage
Autor: Lu, Ping ; Hou, Tianyuan ; Gu, Xiangyong ; Li, Pixu
É parte de: Organic letters, 1900
Descrição: A mild and high-yielding visible-light-promoted conversion of alkyl benzyl ethers to the alkyl esters or alkyl alcohols was developed. Mechanistic studies provided evidence for a radical chain reaction involving the homolytic cleavage of O-α-sp3 C–H bonds in the substrate as one of the propagation steps. We propose that α-bromoethers are key intermediates in the transformation.
Editor: American Chemical Society
Idioma: Inglês

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