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Strategies for Heterocyclic Construction via Novel Multicomponent Reactions Based on Isocyanides and Nucleophilic Carbenes

Nair, Vijay ; Rajesh, C ; Vinod, A. U ; Bindu, S ; Sreekanth, A. R ; Mathen, J. S ; Balagopal, Lakshmi

Accounts of chemical research, 2003-12, Vol.36 (12), p.899-907 [Periódico revisado por pares]

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Título:
Strategies for Heterocyclic Construction via Novel Multicomponent Reactions Based on Isocyanides and Nucleophilic Carbenes
Autor: Nair, Vijay ; Rajesh, C ; Vinod, A. U ; Bindu, S ; Sreekanth, A. R ; Mathen, J. S ; Balagopal, Lakshmi
Assuntos: Combinatorial Chemistry Techniques - methods ; Cyanides - chemistry ; Cyclization ; Heterocyclic Compounds - chemical synthesis ; Heterocyclic Compounds - chemistry ; Hydrocarbons ; Methane - analogs & derivatives ; Methane - chemistry ; Models, Chemical ; Molecular Conformation ; Molecular Structure ; Stereoisomerism
É parte de: Accounts of chemical research, 2003-12, Vol.36 (12), p.899-907
Notas: ark:/67375/TPS-50V35JS9-P
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SourceType-Scholarly Journals-1
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Descrição: This Account focuses mainly on our recent endeavors in the area of multicomponent reactions (MCRs) involving zwitterionic species generated by the addition of isocyanides and nucleophilic carbenes such as dimethoxycarbene and N-heterocyclic carbenes to activated alkynes. The strategy employed encompasses the interception of 1:1 zwitterionic species, generated in situ with a wide range of electrophiles. The new MCRs developed offer an efficient and convenient entry into several heterocycles of biological and synthetic importance.
Editor: United States: American Chemical Society
Idioma: Inglês

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