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Kinetics and Mechanism of Ferrocenylmethanol Oxidation with and without the Participation of Perchloric Acid in Protic and Aprotic Solvents

Fomin, V. M. ; Shuklina, N. N.

Russian Journal of Physical Chemistry A, 2022-10, Vol.96 (10), p.2121-2128 [Periódico revisado por pares]

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Título:
Kinetics and Mechanism of Ferrocenylmethanol Oxidation with and without the Participation of Perchloric Acid in Protic and Aprotic Solvents
Autor: Fomin, V. M. ; Shuklina, N. N.
Assuntos: Chemical Kinetics and Catalysis ; Chemistry ; Chemistry and Materials Science ; Functional groups ; Iodine ; Kinetics ; Oxidation ; Oxidizing agents ; Perchloric acid ; Physical Chemistry ; Protonation ; Quinones ; Solvents
É parte de: Russian Journal of Physical Chemistry A, 2022-10, Vol.96 (10), p.2121-2128
Descrição: Results from studying the kinetics and mechanism of the oxidation of ferrocenylmethanol FcCH 2 OH with the participation of iodine in protic and aprotic solvents demonstrate the ability of I 2 to act as an oxidizing agent with and without the participation of strong acid HClO 4 . The possibility of ferrocenium cations forming upon the protonation of FcCH 2 OH is due to characteristic features of the oxidation of the metal complex, compared to its oxidation with the participation of p -quinone, which displays oxidizing properties only in the presence of acids, and the oxidation of ferrocene with the participation of iodine, which contains no functional groups capable of protonation.
Editor: Moscow: Pleiades Publishing
Idioma: Inglês

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