Kinetics and Mechanism of Ferrocenylmethanol Oxidation with and without the Participation of Perchloric Acid in Protic and Aprotic Solvents
ABCD PBi
Kinetics and Mechanism of Ferrocenylmethanol Oxidation with and without the Participation of Perchloric Acid in Protic and Aprotic Solvents
Autor:
Fomin
,
V
.
M
.
;
Shuklina, N. N.
Assuntos:
Chemical Kinetics and Catalysis
;
Chemistry
;
Chemistry and Materials Science
;
Functional groups
;
Iodine
;
Kinetics
;
Oxidation
;
Oxidizing agents
;
Perchloric acid
;
Physical Chemistry
;
Protonation
;
Quinones
;
Solvents
É parte de:
Russian Journal of Physical Chemistry A, 2022-10, Vol.96 (10), p.2121-2128
Descrição:
Results from studying the kinetics and mechanism of the oxidation of ferrocenylmethanol FcCH 2 OH with the participation of iodine in protic and aprotic solvents demonstrate the ability of I 2 to act as an oxidizing agent with and without the participation of strong acid HClO 4 . The possibility of ferrocenium cations forming upon the protonation of FcCH 2 OH is due to characteristic features of the oxidation of the metal complex, compared to its oxidation with the participation of p -quinone, which displays oxidizing properties only in the presence of acids, and the oxidation of ferrocene with the participation of iodine, which contains no functional groups capable of protonation.
Editor:
Moscow: Pleiades Publishing
Idioma:
Inglês