skip to main content
Idioma:
Tipo de recurso Mostra resultados com: Mostra resultados com: Índice

Modulation by Amino Acids: Toward Superior Control in the Synthesis of Zirconium Metal-Organic Frameworks

Gutov, Oleksii V. ; Molina, Sonia ; Escudero-Adán, Eduardo C. ; Shafir, Alexandr

Chemistry : a European journal, 2016-09, Vol.22 (38), p.13582-13587 [Periódico revisado por pares]

Germany: Blackwell Publishing Ltd

Texto completo disponível

Citações Citado por
  • Título:
    Modulation by Amino Acids: Toward Superior Control in the Synthesis of Zirconium Metal-Organic Frameworks
  • Autor: Gutov, Oleksii V. ; Molina, Sonia ; Escudero-Adán, Eduardo C. ; Shafir, Alexandr
  • Assuntos: Amino acids ; Ligands ; Metal-organic frameworks ; modulated synthesis ; Modulation ; Modulators ; Particle size ; proline ; Synthesis ; Zirconium
  • É parte de: Chemistry : a European journal, 2016-09, Vol.22 (38), p.13582-13587
  • Notas: ArticleID:CHEM201600898
    istex:8343073B6796F24C880DA30512886007FD314F7C
    EC - No. FP7-PEOPLE-2013-IIF-623725
    Fundació ICIQ, MINECO - No. CTQ2013-46705-R; No. 2014-2018 Severo Ochoa Excellence Accreditation SEV-2013-0319
    Generalitat de Catalunya - No. 2014 SGR 1192
    ark:/67375/WNG-3SJXKF9W-T
    CELLEX Foundation
    ObjectType-Article-1
    SourceType-Scholarly Journals-1
    ObjectType-Feature-2
    content type line 23
  • Descrição: The synthesis of zirconium metal–organic frameworks (Zr MOFs) modulated by various amino acids, including l‐proline, glycine, and l‐phenylalanine, is shown to be a straightforward approach toward functional‐group incorporation and particle‐size control. High yields in Zr‐MOF synthesis are achieved by employing 5 equivalents of the modulator at 120 °C. At lower temperatures, the method provides a series of Zr MOFs with increased particle size, including many suitable for single‐crystal X‐ray diffraction studies. Furthermore, amino acid modulators can be incorporated at defect sites in Zr MOFs with an amino acid/ligand ratio of up to 1:1, depending on the ligand structure and reaction conditions. The MOFs obtained through amino acid modulation exhibit an improved CO2‐capture capacity relative to nonfunctionalized materials. Controlled assembly: Zirconium metal–organic frameworks (Zr MOFs) are synthesized through amino acid modulation in a straightforward approach toward functional‐group incorporation and particle‐size control. This method provides a series of Zr MOFs with increased particle size and an improved CO2‐capture capacity relative to nonfunctionalized materials.
  • Editor: Germany: Blackwell Publishing Ltd
  • Idioma: Inglês
Links
Voltar para lista de resultados

  • Realização: ABCD-USP USP   Logos de Redes Sociais: Freepik

Buscando em bases de dados remotas. Favor aguardar.