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Hydroformylation in Aqueous Biphasic Media Assisted by Molecular Receptors

Hapiot, Frédéric ; Bricout, Hervé ; Tilloy, Sébastien ; Monflier, Eric

Hydroformylation for Organic Synthesis, 2013, Vol.342, p.49-78 [Periódico revisado por pares]

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Título:
Hydroformylation in Aqueous Biphasic Media Assisted by Molecular Receptors
Autor: Hapiot, Frédéric ; Bricout, Hervé ; Tilloy, Sébastien ; Monflier, Eric
Assuntos: Biphasic catalysis ; Calixarenes ; Chemical Sciences ; Cyclodextrins ; Inclusion complexes ; Molecular recognition
É parte de: Hydroformylation for Organic Synthesis, 2013, Vol.342, p.49-78
Notas: ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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Descrição: The role of molecular receptors in aqueous biphasic hydroformylation of higher olefins is highlighted through a detailed analysis of their molecular recognition properties. The behavior of cyclodextrins and calixarenes as molecular receptors is especially emphasized and discussed. Their supramolecular interactions with the substrates and the water-soluble ligands proved to be an essential parameter guiding the reaction performances. The hydroformylation activity and chemo- and regio-selectivities can thus be accurately controlled by a suitable match between the receptor and the reaction components. Development outlooks are also presented.
Títulos relacionados: Topics in Current Chemistry
Editor: Berlin, Heidelberg: Springer Berlin Heidelberg
Idioma: Inglês

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